Product ID:102 9610,PAGI-SET DIRECT NEGATIVE DEVELOPER AND REPLENISHER
MSDS Date:01/12/1999
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKMNM

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

2-ETHYLAMINOETHANOL

CAS: 110-73-6

RTECS: KK9100000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

HYDROQUINONE

CAS: 123-31-9

RTECS: MX3500000

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

POTASSIUM HYDROXIDE

CAS: 1310-58-3

RTECS: TT2100000

OSHA PEL NONE

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:DERMAL LD-50: 10-20 ML/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATO RY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES BURNS. SKIN: CAUSES BURNS. HARMFUL IF ABSORBED THROUGH
SKIN. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF
SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, H IVES,
FAINTNESS, WEAKNESS AND DIARRHEA.
Explanation of Carcinogenicity:-CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NO NE - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE.
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. EYES: CAUSES
BURNS.SKIN: CAUSES BURNS. INGES TION: MAY CAUSE BURNS OF THE
GASTROINTESTINAL TRACT IF SWALLOWED. SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS A ND DIARRHEA.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IMMEDIATELY. WASH
CONTAMINATED CLOTHING BEF ORE REUSE. DESTROY OR THOROUGHLY CLEAN
CONTAMINATED SHOES. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM
A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL A PHYSICIAN OR P OISON CONTROL CENTER IMMEDIATELY.

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID
BREATHING MIST OR VAPOR AT CONCENTRATIONS GREATER THAN THE EXPOSURE
LIMITS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A
FACE SHIELD.
Other Protective Equipment:PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK
OF EXPOSURE. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.

HCC:B1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F): 24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:(WATER = 1): 1.079
pH:10.8
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:PHYSICAL FORM: LIQUID COLOR: TAN ODOR: AMINE
Percent Volatiles by Volume:89 % WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
SULFUR DIOXIDE, NITROGEN OXIDES (NOX).
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: THE
TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY
INVESTIGATED AND ITS HANDLING AND USE MAY PRESENT ADDITIONAL
HAZARDS. CONTAINS: HYDROQUINONE. IN F-344 R ATS, CHRONIC ORAL
ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN THE FORMATION OF
BENIGN KIDNEY TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY. ACUTE
TOXICITY DATA: DERMAL LD-50: 10-20 ML/KG SKIN IRRITATION:
STRONG

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A MODERATE
BIOCHEMICAL OXYGEN DEMAND AND MAY CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A HIGH POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS, A
MODERATE P OTENTIAL TO AFFECT SECONDARY WASTE TREATMENT MICROBIAL
METABOLISM, A MODERATE POTENTIAL TO AFFECT THE GERMINATION AND/OR
EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL TO PERSIST IN THE
ENVIRONMENT, A LOW POTENTIAL TO BIOCONCENTRATE. AFTER DILUTION
WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE
TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE
ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:HEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: HYDROQUINONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE